Literature DB >> 19214315

Neptunium(vi) chain and neptunium(vi/v) mixed valence cluster complexes.

Stéphanie M Cornet1, L Jonas L Häller, Mark J Sarsfield, David Collison, Madeleine Helliwell, Iain May, Nikolas Kaltsoyannis.   

Abstract

The synthesis of [Np(VI)O(2)Cl(2)(thf)](n) offers the potential for more detailed exploration of neptunyl(vi) chemistry, while the synthesis of the mixed valence cluster complex [{Np(VI)O(2)Cl(2)}{Np(V)O(2)Cl(thf)(3)}(2)] allows molecular neptunyl(v) 'cation-cation' interactions to be probed.

Entities:  

Year:  2009        PMID: 19214315     DOI: 10.1039/b818973k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Double uranium oxo cations derived from uranyl by borane or silane reduction.

Authors:  Bradley E Cowie; Gary S Nichol; Jason B Love; Polly L Arnold
Journal:  Chem Commun (Camb)       Date:  2018-04-12       Impact factor: 6.222

  1 in total

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