Literature DB >> 19206128

Stereoselective synthesis of cis-beta-methyl- and phenyl-substituted alkenylboronates by platinum-catalyzed dehydrogenative borylation.

Toshimichi Ohmura1, Yuta Takasaki, Hideki Furukawa, Michinori Suginome.   

Abstract

Changing places: Intramolecular B(pin)/H exchange took place in the presence of a platinum-phosphane catalyst, giving synthetically useful cis-beta-methyl-substituted alkenylboronates stereoselectively (see scheme; B(pin) = 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl).

Entities:  

Year:  2009        PMID： 19206128     DOI： 10.1002/anie.200805406

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  2 in total

1.  Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes.

Authors:  Azusa Kondoh; Timothy F Jamison
Journal:  Chem Commun (Camb)       Date:  2010-01-05       Impact factor: 6.222

2.  Copper-Catalyzed Triboration of Terminal Alkynes Using B2 pin2 : Efficient Synthesis of 1,1,2-Triborylalkenes.

Authors:  Xiaocui Liu; Wenbo Ming; Alexandra Friedrich; Florian Kerner; Todd B Marder
Journal:  Angew Chem Int Ed Engl       Date:  2019-11-19       Impact factor: 15.336
  2 in total

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