| Literature DB >> 19199655 |
Manon Chaumontet1, Pascal Retailleau, Olivier Baudoin.
Abstract
An efficient synthesis of polycyclic molecules has been performed by a sequence involving palladium-catalyzed C-H activation and [4 + 2] cycloaddition. The intermediate benzocyclobutenes underwent a microwave-enhanced electrocyclic ring-opening/cycloaddition process with complete torquoselectivity and diastereoselectivity.Entities:
Year: 2009 PMID: 19199655 DOI: 10.1021/jo802471u
Source DB: PubMed Journal: J Org Chem ISSN: 0022-3263 Impact factor: 4.354