Literature DB >> 19199438

Spin crossover by encapsulation.

Kosuke Ono1, Michito Yoshizawa, Munetaka Akita, Tatsuhisa Kato, Yoshihide Tsunobuchi, Shin-Ichi Ohkoshi, Makoto Fujita.   

Abstract

Encapsulation by synthetic hosts can transform the spin states of square planar Ni(II)(acen) and Co(II)(tap) complexes. Upon encapsulation, the red Ni(II) diamagnetic state was converted into a green paramagnetic state, whereas the Co(II) low spin (S = 1/2) state was changed into a coupled (S = 1/2 and S = 3/2) state. The host cages are noninnocent and host-guest interactions within the confined cavity influence the resultant properties of the enclathrated metal complexes.

Entities:  

Year:  2009        PMID： 19199438     DOI： 10.1021/ja8089894

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  5 in total

Review 1.  Supramolecular coordination: self-assembly of finite two- and three-dimensional ensembles.

Authors:  Rajesh Chakrabarty; Partha Sarathi Mukherjee; Peter J Stang
Journal:  Chem Rev       Date:  2011-08-24       Impact factor: 60.622

2.  Assembling Pentatopic Terpyridine Ligands with Three Types of Coordination Moieties into a Giant Supramolecular Hexagonal Prism: Synthesis, Self-Assembly, Characterization, and Antimicrobial Study.

Authors:  Heng Wang; Chung-Hao Liu; Kun Wang; Minghui Wang; Hao Yu; Sneha Kandapal; Robert Brzozowski; Bingqian Xu; Ming Wang; Shuai Lu; Xin-Qi Hao; Prahathees Eswara; Mu-Ping Nieh; Jianfeng Cai; Xiaopeng Li
Journal:  J Am Chem Soc       Date:  2019-09-25       Impact factor: 15.419

3.  Self-Assembled M₂L₄ Nanocapsules: Synthesis, Structure and Host-Guest Recognition Toward Square Planar Metal Complexes.

Authors:  Christophe Desmarets; Thierry Ducarre; Marie Noelle Rager; Geoffrey Gontard; Hani Amouri
Journal:  Materials (Basel)       Date:  2014-01-09       Impact factor: 3.623

4.  Tricoordinate Coinage Metal Complexes with a Redox-Active Tris-(Ferrocenyl)triazine Backbone Feature Triazine-Metal Interactions.

Authors:  Axel Straube; Peter Coburger; Mark R Ringenberg; Evamarie Hey-Hawkins
Journal:  Chemistry       Date:  2020-04-22       Impact factor: 5.236

Review 5.  Structural Flexibility in Metal-Organic Cages.

Authors:  Andrés E Martín Díaz; James E M Lewis
Journal:  Front Chem       Date:  2021-06-17       Impact factor: 5.221
  5 in total

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