Literature DB >> 19199320

Selectivity control in gold-mediated esterification of methanol.

Bingjun Xu1, Xiaoying Liu, Jan Haubrich, Robert J Madix, Cynthia M Friend.   

Abstract

The Midas touch: The low-temperature transformation of methanol to methyl formate, formaldehyde, and formic acid is promoted by atomic oxygen adsorbed on metallic gold (see picture). The reactions occur with O-containing Au nanoparticles formed on Au(111) upon oxidation with ozone at 200 K; the facile esterification to methyl formate occurs well below room temperature.

Entities:  

Year:  2009        PMID： 19199320     DOI： 10.1002/anie.200805404

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  6 in total

1.  The promoting effect of adsorbed carbon monoxide on the oxidation of alcohols on a gold catalyst.

Authors:  Paramaconi Rodriguez; Youngkook Kwon; Marc T M Koper
Journal:  Nat Chem       Date:  2011-12-11       Impact factor: 24.427

2.  Vapour-phase gold-surface-mediated coupling of aldehydes with methanol.

Authors:  Bingjun Xu; Xiaoying Liu; Jan Haubrich; Cynthia M Friend
Journal:  Nat Chem       Date:  2009-11-29       Impact factor: 24.427

3.  Dynamic restructuring drives catalytic activity on nanoporous gold-silver alloy catalysts.

Authors:  Branko Zugic; Lucun Wang; Christian Heine; Dmitri N Zakharov; Barbara A J Lechner; Eric A Stach; Juergen Biener; Miquel Salmeron; Robert J Madix; Cynthia M Friend
Journal:  Nat Mater       Date:  2016-12-19       Impact factor: 43.841

4.  Theoretical study of coupling p-aminothiophenol to hydroazo- and azo-adducts on Au(111).

Authors:  Xiufeng Lang; Yanhong Liang; Siyan Liu; Shanshan Zhao; Woon-Ming Lau
Journal:  J Mol Model       Date:  2016-08-03       Impact factor: 1.810

5.  Identifying key descriptors in surface binding: interplay of surface anchoring and intermolecular interactions for carboxylates on Au(110).

Authors:  Christopher R O'Connor; Fanny Hiebel; Wei Chen; Efthimios Kaxiras; Robert J Madix; Cynthia M Friend
Journal:  Chem Sci       Date:  2018-03-12       Impact factor: 9.825

6.  Toward benchmarking theoretical computations of elementary rate constants on catalytic surfaces: formate decomposition on Au and Cu.

Authors:  Eri Muramoto; Wei Chen; Xiwen Jia; Cynthia M Friend; Philippe Sautet; Robert J Madix
Journal:  Chem Sci       Date:  2021-12-21       Impact factor: 9.825
  6 in total

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