| Literature DB >> 19191357 |
Kenji Ishitake1, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto.
Abstract
Life RAFT: A bulky methacrylate monomer, triphenylmethyl methacrylate (TrMA), was polymerized with reversible addition-fragmentation chain transfer (RAFT) agents. Stereogradient polymers in which the isospecificity increased spontaneously as the monomer concentration decreased were formed by a polymerization-depolymerization equilibrium that can convert a less stable growing polymer terminal into a more stable form (see picture).Entities:
Year: 2009 PMID: 19191357 DOI: 10.1002/anie.200805168
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336