Literature DB >> 19173661

Identification of the water amidogen radical complex.

Courtney P Ennis1, Joseph R Lane, Henrik G Kjaergaard, Allan J McKinley.   

Abstract

The water amidogen radical complex (H(2)O-NH(2)) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H(2)O-NH(2) complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.

Entities:  

Year:  2009        PMID: 19173661     DOI: 10.1021/ja808109m

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  1 in total

1.  Catalytic effect of (H2O) n (n = 1-3) on the HO2 + NH2 → NH3 + 3O2 reaction under tropospheric conditions.

Authors:  Tianlei Zhang; Kai Wang; Zhangyu Qiao; Yongqi Zhang; Lin Geng; Rui Wang; Zhiyin Wang; Caibin Zhao; Linxia Jin
Journal:  RSC Adv       Date:  2018-11-05       Impact factor: 3.361

  1 in total

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