| Literature DB >> 19173648 |
Robert A Moss1, Lei Wang, Karsten Krogh-Jespersen.
Abstract
Difluorodiazirine was generated by the reaction of 2,4-dinitrophenoxyfluorodiazirine with lithium fluoride and 15-crown-5 in HMPA. Laser flash photolysis of difluorodiazirine afforded difluorocarbene (CF(2)). Absolute rate constants and activation parameters were determined for the additions of CF(2) to several alkenes.Entities:
Year: 2009 PMID： 19173648 DOI： 10.1021/ja809370j
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419