| Literature DB >> 19161301 |
Sayuri Hayashi1, Hideki Yorimitsu, Koichiro Oshima.
Abstract
A novel synthetic method for the preparation of tri- or tetrasubstituted epoxides is reported. Treatment of readily available tertiary allyl alcohol with aryl or alkenyl halide under palladium catalysis resulted in arylative cyclization to form the epoxide. The reaction includes intramolecular C-O bond and intermolecular C-C bond construction.Entities:
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Year: 2009 PMID： 19161301 DOI： 10.1021/ja8084065
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419