| Literature DB >> 19153615 |
Ana C Fernandes1, José A Fernandes, Filipe A Almeida Paz, Carlos C Romão.
Abstract
The isolation and structural characterization by X-ray diffraction of (PPh(3))(2)(O)(I)Re(H)OBcat and (PPh(3))(2)(O)(I)Re(H)OBpin from the reaction of ReIO(2)(PPh(3))(2) with the boranes catecholborane (HBcat) and pinacolborane (HBpin) unequivocally shows the first example of activation of B-H bond by a high valent oxo-rhenium complex.Entities:
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Year: 2008 PMID： 19153615 DOI： 10.1039/b816802b
Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390