Literature DB >> 19145617

Perfluoropentaphenylborole.

Cheng Fan1, Warren E Piers, Masood Parvez.   

Abstract

Perfluorination: The fully fluorinated analogue of pentaphenylborole (see structure; B gray, C black, F green) has been prepared using successive transmetallation reactions involving Zr and Sn heterocycles. The highly moisture-sensitive borole is a new member of the perfluoroaryl borane family, a class of antiaromatic compounds of fundamental significance to concepts of aromaticity.

Entities:  

Year:  2009        PMID: 19145617     DOI: 10.1002/anie.200805865

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  6 in total

1.  Direct observation of a borane-silane complex involved in frustrated Lewis-pair-mediated hydrosilylations.

Authors:  Adrian Y Houghton; Juha Hurmalainen; Akseli Mansikkamäki; Warren E Piers; Heikki M Tuononen
Journal:  Nat Chem       Date:  2014-09-28       Impact factor: 24.427

2.  A Cationic NHC-Supported Borole.

Authors:  Tobias Heitkemper; Christian P Sindlinger
Journal:  Chemistry       Date:  2020-08-13       Impact factor: 5.236

3.  Taming the beast: fluoromesityl groups induce a dramatic stability enhancement in boroles.

Authors:  Zuolun Zhang; Robert M Edkins; Martin Haehnel; Marius Wehner; Antonius Eichhorn; Lisa Mailänder; Michael Meier; Johannes Brand; Franziska Brede; Klaus Müller-Buschbaum; Holger Braunschweig; Todd B Marder
Journal:  Chem Sci       Date:  2015-07-13       Impact factor: 9.825

4.  A free boratriptycene-type Lewis superacid.

Authors:  Marcel Henkelmann; Andreas Omlor; Michael Bolte; Volker Schünemann; Hans-Wolfram Lerner; Jozef Noga; Peter Hrobárik; Matthias Wagner
Journal:  Chem Sci       Date:  2021-12-07       Impact factor: 9.825

Review 5.  (Hetero)arene-fused boroles: a broad spectrum of applications.

Authors:  Jiang He; Florian Rauch; Maik Finze; Todd B Marder
Journal:  Chem Sci       Date:  2020-11-24       Impact factor: 9.825

6.  An Extensive Set of Accurate Fluoride Ion Affinities for p-Block Element Lewis Acids and Basic Design Principles for Strong Fluoride Ion Acceptors.

Authors:  Philipp Erdmann; Jonas Leitner; Julia Schwarz; Lutz Greb
Journal:  Chemphyschem       Date:  2020-04-20       Impact factor: 3.102

  6 in total

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