Literature DB >> 19140797

Activation and tuning of green fluorescent protein chromophore emission by alkyl substituent-mediated crystal packing.

Jian Dong1, Kyril M Solntsev, Laren M Tolbert.   

Abstract

O-Alkyl synthetic analogues of the green fluorescent protein chromophore are nonfluorescent in solution but demonstrate a bright emission in the crystalline state. Three-dimensional steady-state and time-resolved emission spectroscopies in the solid state, as well as single-crystal X-ray diffraction, reveal the nature of complex emission in the crystals. A hypsochromic emission shift with an increase of the alkyl size is determined by the monomer-aggregate emission ratio.

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Year:  2009        PMID: 19140797     DOI: 10.1021/ja806962e

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  3 in total

1.  A new twist in the photophysics of the GFP chromophore: a volume-conserving molecular torsion couple.

Authors:  Jamie Conyard; Ismael A Heisler; Yohan Chan; Philip C Bulman Page; Stephen R Meech; Lluís Blancafort
Journal:  Chem Sci       Date:  2018-01-10       Impact factor: 9.825

2.  (Z)-1-(2-Hy-droxy-eth-yl)-4-(2-meth-oxy-benzyl-idene)-2-methyl-1H-imidazol-5(4H)-one.

Authors:  Hongyi Wu; Weihua Wang; Edwin H Walker; Frank R Fronczek
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-03-28

3.  Rational Design for Multicolor Flavone-Based Fluorophores with Aggregation-Induced Emission Enhancement Characteristics and Applications in Mitochondria-Imaging.

Authors:  Liyan Liu; Yaohui Lei; Jianhui Zhang; Na Li; Fan Zhang; Huaqiao Wang; Feng He
Journal:  Molecules       Date:  2018-09-07       Impact factor: 4.411

  3 in total

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