Literature DB >> 19138115

Synthetic studies on N-alkoxyamines: a mild and broadly applicable route starting from nitroxide radicals and aldehydes.

Kai-Uwe Schoening1, Walter Fischer, Stefan Hauck, Alexander Dichtl, Michael Kuepfert.   

Abstract

A broad variety of 2,2,6,6-tetramethylpiperidine-based N-alkoxyamines were prepared in a newly found reaction. By means of a copper-catalyzed fragmentation reaction of aldehyde peroxides in the presence of TEMPO or TEMPO derivatives, N-alkoxyamines were obtained in moderate to good yields.

Entities:  

Year:  2009        PMID: 19138115     DOI: 10.1021/jo802403j

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  1 in total

1.  Switching radical stability by pH-induced orbital conversion.

Authors:  Ganna Gryn'ova; David L Marshall; Stephen J Blanksby; Michelle L Coote
Journal:  Nat Chem       Date:  2013-04-21       Impact factor: 24.427

  1 in total

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