Literature DB >> 19133778

Rhazinilam and quebrachamine derivatives from Yunnan Kopsia arborea.

Yuqiu Wu1, Mayu Suehiro, Mariko Kitajima, Takeshi Matsuzaki, Shusuke Hashimoto, Masato Nagaoka, Rongping Zhang, Hiromitsu Takayama.   

Abstract

Three new rhazinilam-derived alkaloids, kopsiyunnanines C1, C2, and C3, and a new quebrachamine-type alkaloid, kopsiyunnanine D, which possess an unusual methoxymethyl or ethoxymethyl function, were isolated from the aerial parts of Yunnan Kopsia arborea. This is the first report of the presence of these functions in natural alkaloids. The structures and absolute configurations of the alkaloids were determined by spectroscopic methods and confirmed by semisynthesis.

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Year:  2009        PMID: 19133778     DOI: 10.1021/np800489e

Source DB:  PubMed          Journal:  J Nat Prod        ISSN: 0163-3864            Impact factor:   4.050


  3 in total

Review 1.  Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids.

Authors:  Beau P Pritchett; Brian M Stoltz
Journal:  Nat Prod Rep       Date:  2018-06-20       Impact factor: 13.423

2.  Kopsiyunnanines F and isocondylocarpines: new tubotaiwine-type alkaloids from Yunnan Kopsia arborea.

Authors:  Yuqiu Wu; Mariko Kitajima; Noriyuki Kogure; Yunsong Wang; Rongping Zhang; Hiromitsu Takayama
Journal:  J Nat Med       Date:  2009-04-28       Impact factor: 2.343

Review 3.  A comprehensive review on phytochemistry and pharmacology of genus Kopsia: monoterpene alkaloids - major secondary metabolites.

Authors:  Nguyen Quang Hop; Ninh The Son
Journal:  RSC Adv       Date:  2022-07-05       Impact factor: 4.036

  3 in total

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