Literature DB >> 19130533

Hydrogenation of N-acylcarbamates and N-acylsulfonamides catalyzed by a bifunctional [Cp*Ru(PN)] complex.

Masato Ito1, Lee Wei Koo, Akio Himizu, Chika Kobayashi, Ayaka Sakaguchi, Takao Ikariya.   

Abstract

Awakening of the Cp one: The bifunctional complex 1 facilitates the interaction with substrates bearing less electrophilic carbon atoms than ketones, epoxides, and imides. The title reaction was applicable to the reduction of Evans' asymmetric alkylation products to the chiral alcohols along with good recovery of the chiral oxazolidinone auxiliary. EWG = electron-withdrawing group.

Entities:  

Year:  2009        PMID： 19130533     DOI： 10.1002/anie.200805307

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  5 in total

1.  N-activated β-lactams as versatile reagents for acyl carrier protein labeling.

Authors:  Gitanjeli Prasad; Jon W Amoroso; Lawrence S Borketey; Nathan A Schnarr
Journal:  Org Biomol Chem       Date:  2012-01-31       Impact factor: 3.876

2.  Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO.

Authors:  Ekambaram Balaraman; Chidambaram Gunanathan; Jing Zhang; Linda J W Shimon; David Milstein
Journal:  Nat Chem       Date:  2011-07-22       Impact factor: 24.427

3.  (Acetonitrile-κN)[2-(diphenylphosphan-yl)ethanamine-κN,P][(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl]iron(II) hexafluoridophosphate tetrahydrofuran monosolvate.

Authors:  Kajin Lee; Frank Rominger; Michael Limbach
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-07-23

4.  Highly chemoselective reduction of amides (primary, secondary, tertiary) to alcohols using SmI2/amine/H2O under mild conditions.

Authors:  Michal Szostak; Malcolm Spain; Andrew J Eberhart; David J Procter
Journal:  J Am Chem Soc       Date:  2014-01-31       Impact factor: 15.419

5.  Multifaceted catalytic hydrogenation of amides via diverse activation of a sterically confined bipyridine-ruthenium framework.

Authors:  Takashi Miura; Masayuki Naruto; Katsuaki Toda; Taiki Shimomura; Susumu Saito
Journal:  Sci Rep       Date:  2017-05-16       Impact factor: 4.379
  5 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.