Literature DB >> 19125343

Fluorous Lewis acids and phase transfer catalysts.

Chun Cai1, Wen-Bin Yi, Wei Zhang, Ming-Gui Shen, Mei Hong, Li-Yan Zeng.   

Abstract

The new phase-separation and immobilization technique known as fluorous biphase system (FBS) has become an active topic among researchers in both industry and academia. A series of fluorous biphasic reactions catalyzed by Lewis acid-type metal perfluorooctanesulfonates and metal bis(perfluorooctanesulfonyl)amides are reviewed in this paper. The recent development of fluorous phase transfer catalyst (PTC) is also discussed.

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Year:  2009        PMID: 19125343     DOI: 10.1007/s11030-008-9103-y

Source DB:  PubMed          Journal:  Mol Divers        ISSN: 1381-1991            Impact factor:   2.943


  43 in total

1.  Selective formation of alpha-methylene-beta-amino acid derivatives through the aza version of the Baylis-Hillman reaction.

Authors:  D Balan; H Adolfsson
Journal:  J Org Chem       Date:  2001-09-21       Impact factor: 4.354

2.  Rare-earth metal triflates in organic synthesis.

Authors:  Shū Kobayashi; Masaharu Sugiura; Hidetoshi Kitagawa; William W-L Lam
Journal:  Chem Rev       Date:  2002-06       Impact factor: 60.622

3.  Homovanillic acid, vanillylmandelic acid and 5-hydroxyindole-3-acetic acid are undetectable in urine of the muskrat.

Authors:  M Yoshioka; A Yoshida; Y Ichihashi; H Saito
Journal:  Chem Pharm Bull (Tokyo)       Date:  1985-05       Impact factor: 1.645

4.  Semisynthetic cephalosporins. Synthesis and structure-activity relationships of 7-mandelamido-3-cephem-4-carboxylic acids.

Authors:  J R Hoover; G L Dunn; D R Jakas; L L Lam; J J Taggart; J R Guarini; L Phillips
Journal:  J Med Chem       Date:  1974-01       Impact factor: 7.446

5.  Synthesis and biological activity of novel nonnucleoside inhibitors of HIV-1 reverse transcriptase. 2-Aryl-substituted benzimidazoles.

Authors:  T Roth; M L Morningstar; P L Boyer; S H Hughes; R W Buckheit; C J Michejda
Journal:  J Med Chem       Date:  1997-12-19       Impact factor: 7.446

6.  Synthesis and photophysical properties of new fluorinated benzo[c]xanthene dyes as intracellular pH indicators.

Authors:  J Liu; Z Diwu; W Y Leung
Journal:  Bioorg Med Chem Lett       Date:  2001-11-19       Impact factor: 2.823

7.  Electrophilic aromatic nitration using perfluorinated rare earth metal salts in fluorous phase.

Authors:  Min Shi; Shi-Cong Cui
Journal:  Chem Commun (Camb)       Date:  2002-05-07       Impact factor: 6.222

8.  Atom-efficient electrophilic aromatic nitration by dinitrogen pentoxide catalysed by zirconium(IV) 2,4-pentanedionate.

Authors:  Adrian J Hill; Ross W Millar; John P B Sandall
Journal:  Org Biomol Chem       Date:  2003-11-06       Impact factor: 3.876

9.  Polyfluorinated quaternary ammonium salts of polyoxometalate anions: fluorous biphasic oxidation catalysis with and without fluorous solvents.

Authors:  Galia Maayan; Richard H Fish; Ronny Neumann
Journal:  Org Lett       Date:  2003-10-02       Impact factor: 6.005

10.  Fluorous biphasic catalysis: synthesis and characterization of copper(I) and copper(II) fluoroponytailed 1,4,7-Rf-TACN and 2,2'-Rf-bipyridine complexes--their catalytic activity in the oxidation of hydrocarbons, olefins, and alcohols, including mechanistic implications.

Authors:  María Contel; Cristina Izuel; Mariano Laguna; Pedro R Villuendas; Pablo J Alonso; Richard H Fish
Journal:  Chemistry       Date:  2003-09-05       Impact factor: 5.236

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