Literature DB >> 19115853

Insertion polymerization of acrylate.

Damien Guironnet1, Philipp Roesle, Thomas Rünzi, Inigo Göttker-Schnetmann, Stefan Mecking.   

Abstract

Multiple insertions of acrylate in copolymerization with ethylene, and an insertion homo-oligomerization of methyl acrylate were observed for the first time. Key to these findings, and to mechanistic insights reported, are labile-substituted complexes as catalyst precursors.

Entities:  

Year:  2009        PMID: 19115853     DOI: 10.1021/ja808017n

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  4 in total

1.  Breaking the regioselectivity rule for acrylate insertion in the Mizoroki-Heck reaction.

Authors:  Philipp Wucher; Lucia Caporaso; Philipp Roesle; Francesco Ragone; Luigi Cavallo; Stefan Mecking; Inigo Göttker-Schnetmann
Journal:  Proc Natl Acad Sci U S A       Date:  2011-05-11       Impact factor: 11.205

2.  Ultrahigh Branching of Main-Chain-Functionalized Polyethylenes by Inverted Insertion Selectivity.

Authors:  Yuxing Zhang; Chaoqun Wang; Stefan Mecking; Zhongbao Jian
Journal:  Angew Chem Int Ed Engl       Date:  2020-07-06       Impact factor: 15.336

3.  Encapsulation of catalyst in block copolymer micelles for the polymerization of ethylene in aqueous medium.

Authors:  Camille Boucher-Jacobs; Muhammad Rabnawaz; Joshua S Katz; Ralph Even; Damien Guironnet
Journal:  Nat Commun       Date:  2018-02-26       Impact factor: 14.919

4.  Ligand-controlled insertion regioselectivity accelerates copolymerisation of ethylene with methyl acrylate by cationic bisphosphine monoxide-palladium catalysts.

Authors:  Yusuke Mitsushige; Brad P Carrow; Shingo Ito; Kyoko Nozaki
Journal:  Chem Sci       Date:  2015-11-03       Impact factor: 9.825

  4 in total

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