| Literature DB >> 19105716 |
Cai-Ming Liu1, De-Qing Zhang, Dao-Ben Zhu.
Abstract
The wheel-shaped heptanuclear cluster complex {[Mn(4)Na(3)(thmp)(2)(acac)(6)(H(2)O)(6)]CH(3)COO} x 4 H(2)O is the first heterometallic mixed-valent disklike compound with apical alkali-metal ions. The weak ferromagnetic interaction between the central Mn(4+) ion and the peripheral Mn(2+) ones leads to a high-spin ground state (S = 9).Entities:
Year: 2009 PMID： 19105716 DOI： 10.1021/ic8018474
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165