| Literature DB >> 19101185 |
Konstantin A Kozhanov1, Michael P Bubnov, Vladimir K Cherkasov, Georgy K Fukin, Nina N Vavilina, Larisa Yu Efremova, Gleb A Abakumov.
Abstract
A square-pyramidal mixed-halogen nickel(III) NCN-pincer complex (PipeNCN)NiClBr (where PipeNCN=2,6-bis(piperidinomethyl)phenyl) was structurally characterized. Bromine occupies apical position; pincer ligand and chlorine atom are in the basal plane. EPR detects that complex in solution exists as a mixture of two structural isomers with bromine or chlorine atoms in the top of pyramid.Entities:
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Year: 2008 PMID： 19101185 DOI： 10.1016/j.jmr.2008.11.012
Source DB: PubMed Journal: J Magn Reson ISSN： 1090-7807 Impact factor: 2.229