Literature DB >> 19099492

Palladium-catalyzed cross coupling reaction of benzyl bromides with diazoesters for stereoselective synthesis of (E)-alpha,beta-diarylacrylates.

Wing-Yiu Yu1, Yuk-Tai Tsoi, Zhongyuan Zhou, Albert S C Chan.   

Abstract

A Pd-catalyzed cross-coupling reaction of benzyl bromides with alpha-aryldiazoesters is described, and E-alpha,beta-diarylacrylates were obtained in good yields and excellent E-to-Z selectivity (>20:1).

Entities:  

Mesh:

Substances:

Year:  2009        PMID: 19099492     DOI: 10.1021/ol8026076

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Direct stereoselective α-arylation of unmodified enals using an organocatalytic cross-coupling-like reaction.

Authors:  Xixi Song; Aiguo Song; Fang Zhang; He-Xing Li; Wei Wang
Journal:  Nat Commun       Date:  2011-11-08       Impact factor: 14.919

2.  P(NMe2)3-Mediated Umpolung Alkylation and Nonylidic Olefination of α-Keto Esters.

Authors:  Sunewang Rixin Wang; Alexander T Radosevich
Journal:  Org Lett       Date:  2015-07-15       Impact factor: 6.005

  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.