Literature DB >> 19082121

Catalytic asymmetric hydrogenation of alpha-amino-beta-keto ester hydrochlorides using homogeneous chiral nickel-bisphosphine complexes through DKR.

Yasumasa Hamada1, Yu Koseki, Takefumi Fujii, Tsukuru Maeda, Takuya Hibino, Kazuishi Makino.   

Abstract

Homogeneous chiral nickel-bisphosphine complexes catalyze the asymmetric hydrogenation of alpha-amino-beta-keto ester hydrochlorides through dynamic kinetic resolution to efficiently afford anti-beta-hydroxy-alpha-amino esters with high diastereo- and enantioselectivities.

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Year:  2008        PMID： 19082121     DOI： 10.1039/b816524f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.

Authors:  Vikram Bhat; Eric R Welin; Xuelei Guo; Brian M Stoltz
Journal:  Chem Rev       Date:  2017-02-06       Impact factor: 60.622

2.  Ruthenium-catalyzed asymmetric hydrogenation of aromatic and heteroaromatic ketones using cinchona alkaloid-derived NNP ligands.

Authors:  Ling Zhang; Qian Chen; Linlin Li; Jian Jiang; Hao Sun; Li Li; Ting Liu; Lin Zhang; Chun Li
Journal:  RSC Adv       Date:  2022-05-18       Impact factor: 4.036

3.  Nickel-catalyzed asymmetric hydrogenation of β-acylamino nitroolefins: an efficient approach to chiral amines.

Authors:  Wenchao Gao; Hui Lv; Tonghuan Zhang; Yuhong Yang; Lung Wa Chung; Yun-Dong Wu; Xumu Zhang
Journal:  Chem Sci       Date:  2017-07-04       Impact factor: 9.825

4.  Nickel-Catalyzed Asymmetric Hydrogenation of Cyclic Sulfamidate Imines: Efficient Synthesis of Chiral Cyclic Sulfamidates.

Authors:  Yuanhua Liu; Zhiyuan Yi; Xuefeng Tan; Xiu-Qin Dong; Xumu Zhang
Journal:  iScience       Date:  2019-07-04

5.  Computational Prediction of Ammonia-Borane Dehydrocoupling and Transfer Hydrogenation of Ketones and Imines Catalyzed by SCS Nickel Pincer Complexes.

Authors:  Bing Qiu; Wan Wang; Xinzheng Yang
Journal:  Front Chem       Date:  2019-09-13       Impact factor: 5.221

6.  Enantioselective synthesis of anti-3-alkenyl-2-amido-3-hydroxy esters: application to the total synthesis of (+)-alexine.

Authors:  Lu Yu; Peter Somfai
Journal:  RSC Adv       Date:  2019-01-21       Impact factor: 4.036
  6 in total

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