Literature DB >> 19072612

Gold(I) chloride coordinated 3-hexyne.

Jiang Wu1, Peter Kroll, H V Rasika Dias.   

Abstract

A linear gold(I) complex featuring a simple, unstrained alkyne has been synthesized using AuCl and 3-hexyne and characterized using X-ray crystallography. Density functional theory calculations show that sigma donation from alkyne --> Au dominates over the Au --> alkyne pi back-donation.

Entities:  

Year:  2009        PMID： 19072612     DOI： 10.1021/ic8020854

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  5 in total

1.  Direct Evidence for the Origin of Bis-Gold Intermediates: Probing Gold Catalysis with Mass Spectrometry.

Authors:  Mei Lu; Yijin Su; Pengyi Zhao; Xiaohan Ye; Yi Cai; Xiaodong Shi; Eric Masson; Fengyao Li; J Larry Campbell; Hao Chen
Journal:  Chemistry       Date:  2018-01-17       Impact factor: 5.236

2.  Two metals are better than one in the gold catalyzed oxidative heteroarylation of alkenes.

Authors:  Ekaterina Tkatchouk; Neal P Mankad; Diego Benitez; William A Goddard; F Dean Toste
Journal:  J Am Chem Soc       Date:  2011-08-23       Impact factor: 15.419

3.  Synthesis and equilibrium binding studies of cationic, two-coordinate gold(I) π-alkyne complexes.

Authors:  Timothy J Brown; Ross A Widenhoefer
Journal:  J Organomet Chem       Date:  2011-03-15       Impact factor: 2.369

4.  Structure and reactivity of alkyne-chelated ruthenium alkylidene complexes.

Authors:  Kung-Pern Wang; Sang Young Yun; Daesung Lee; Donald J Wink
Journal:  J Am Chem Soc       Date:  2009-10-28       Impact factor: 15.419

5.  An element through the looking glass: exploring the Au-C, Au-H and Au-O energy landscape.

Authors:  Dragoş-Adrian Roşca; Joseph A Wright; Manfred Bochmann
Journal:  Dalton Trans       Date:  2015-11-20       Impact factor: 4.390
  5 in total

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