| Literature DB >> 19072124 |
Luis F Piedra-Garza1, Michael H Dickman, Ovidiu Moldovan, Hans Joachim Breunig, Ulrich Kortz.
Abstract
The dimeric, sandwich-type tungstophosphate [{PhSbOH}(3)(A-alpha-PW(9)O(34))(2)](9-) (1) has idealized D(3h) symmetry and represents the first organoantimony-containing polyoxometalate. Polyanion 1 was synthesized in an aqueous, acidic medium via three different routes and was fully characterized in the solid state by X-ray diffraction, IR, and thermogravimetric analysis and in solution by multinuclear NMR ((1)H, (13)C, (31)P, and (183)W).Entities:
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Year: 2009 PMID： 19072124 DOI： 10.1021/ic8021694
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165