Literature DB >> 19072056

Anionic oxidative polymerization: the synthesis of poly(phenylenedicyanovinylene) (PPCN2V).

Ryan M Moslin1, Trisha L Andrew, Steven E Kooi, Timothy M Swager.   

Abstract

A new polymerization technique that allows for the first-ever synthesis of poly(phenylenedicyanovinylene)s (PPCN2Vs) is described. PPCN2Vs, with their high electron affinities and structural versatility, seem ideally suited to address the need for new n-type polymers. Remarkably the polymers presented herein become more photoluminescent, in the thin film, under continuous irradiation.

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Year:  2009        PMID: 19072056     DOI: 10.1021/ja808256n

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  1 in total

1.  Triptycene diols: a strategy for synthesizing planar π systems through catalytic conversion of a poly(p-phenylene ethynylene) into a poly(p-phenylene vinylene).

Authors:  Brett VanVeller; Dale Robinson; Timothy M Swager
Journal:  Angew Chem Int Ed Engl       Date:  2011-12-23       Impact factor: 15.336

  1 in total

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