Literature DB >> 19067443

Vaporisation of a dicationic ionic liquid.

Kevin R J Lovelock1, Alexey Deyko, Jo-Anne Corfield, Peter N Gooden, Peter Licence, Robert G Jones.   

Abstract

Highest heat of vaporization yet: The dicationic ionic liquid [C(3)(C(1)Im)(2)][Tf(2)N](2) evaporates as a neutral ion triplet. These neutral ion triplets can then be ionised to form singly and doubly charged ions. The mass spectrum exhibits the dication attached to one remaining anion, and the naked dication itself (see picture).

Entities:  

Year:  2009        PMID: 19067443     DOI: 10.1002/cphc.200800690

Source DB:  PubMed          Journal:  Chemphyschem        ISSN: 1439-4235            Impact factor:   3.102


  2 in total

1.  Cation-Anion Interactions, Stability, and IR Spectra of Dicationic Amino Acid-Based Ionic Liquids Probed Using Density Functional Theory.

Authors:  Muraledharan Shyama; Senthilkumar Lakshmipathi
Journal:  J Mol Model       Date:  2021-05-23       Impact factor: 1.810

Review 2.  Quantifying intermolecular interactions of ionic liquids using cohesive energy densities.

Authors:  Kevin R J Lovelock
Journal:  R Soc Open Sci       Date:  2017-12-06       Impact factor: 2.963

  2 in total

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