| Literature DB >> 19053575 |
Marc Presset1, Yoann Coquerel, Jean Rodriguez.
Abstract
The microwave-assisted Wolff rearrangement of cyclic 2-diazo-1,3-diketones performed in the presence of a stoichiometric amount of alcohol, amine, or thiol is an efficient, user, and environmentally friendly synthetic protocol for the synthesis of alpha-carbonylated cycloalkanones. This approach proves superior to existing protocols in scope and eco-compatibility.Entities:
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Year: 2009 PMID： 19053575 DOI： 10.1021/jo8021567
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354