| Literature DB >> 19049285 |
Yuichi Kajita1, Takuya Kurahashi, Seijiro Matsubara.
Abstract
An intermolecular nickel-catalyzed addition reaction has been developed where phthalic anhydrides react with alkynes to afford substituted isocoumarins. A mechanistic rationale is proposed, implying reductive elimination of Ni(0) promoted by ZnCl(2) cocatalyst as the key step of the catalytic cycle.Entities:
Mesh:
Substances:
Year: 2008 PMID: 19049285 DOI: 10.1021/ja806569h
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419