Literature DB >> 19046077

Base-mediated conversion of hydrazine to diazene and dinitrogen at an iron center.

Leslie D Field1, Hsiu L Li, Alison M Magill.   

Abstract

The treatment of the hydrazine complex cis-[Fe(N(2)H(4))(dmpe)(2)](2+) with base afforded the diazene complex cis-[Fe(N(2)H(2))(dmpe)(2)]. This reaction is reversed by the treatment of the diazene complex with a mild acid, while treatment of the hydrazine complex with a mixture of KOBu(t) and Bu(t)Li afforded the dinitrogen complex [Fe(N(2))(dmpe)(2)].

Entities:  

Mesh：

Substances：

Year:  2009        PMID： 19046077     DOI： 10.1021/ic801856q

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  8 in total

Review 1.  Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes.

Authors:  Matthew J Chalkley; Marcus W Drover; Jonas C Peters
Journal:  Chem Rev       Date:  2020-04-30       Impact factor: 60.622

2.  A five-coordinate phosphino/acetate iron(II) scaffold that binds N2, N2H2, N2H4, and NH3 in the sixth site.

Authors:  Caroline T Saouma; Curtis E Moore; Arnold L Rheingold; Jonas C Peters
Journal:  Inorg Chem       Date:  2011-10-17       Impact factor: 5.165

3.  Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor.

Authors:  Sidney E Creutz; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2014-01-09       Impact factor: 15.419

4.  A Sulfide-Bridged Diiron(II) Complex with a cis-N2H4Ligand.

Authors:  Bryan D Stubbert; Javier Vela; William W Brennessel; Patrick L Holland
Journal:  Z Anorg Allg Chem       Date:  2013-07-01       Impact factor: 1.492

5.  Synthesis of diamidopyrrolyl molybdenum complexes relevant to reduction of dinitrogen to ammonia.

Authors:  J M Chin; R R Schrock; P Müller
Journal:  Inorg Chem       Date:  2010-09-06       Impact factor: 5.165

6.  Triggering N(2) uptake via redox-induced expulsion of coordinated NH(3) and N(2) silylation at trigonal bipyramidal iron.

Authors:  Yunho Lee; Neal P Mankad; Jonas C Peters
Journal:  Nat Chem       Date:  2010-05-16       Impact factor: 24.427

7.  Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron.

Authors:  K Cory Macleod; Patrick L Holland
Journal:  Nat Chem       Date:  2013-05-26       Impact factor: 24.427

8.  Activation of ammonia and hydrazine by electron rich Fe(ii) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe(iii) amido intermediate.

Authors:  Lucie Nurdin; Yan Yang; Peter G N Neate; Warren E Piers; Laurent Maron; Michael L Neidig; Jian-Bin Lin; Benjamin S Gelfand
Journal:  Chem Sci       Date:  2020-12-22       Impact factor: 9.825
  8 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.