| Literature DB >> 19007180 |
Roberto Fernández de la Pradilla1, Alejandro Castellanos, Iñaki Osante, Ignacio Colomer, Mateo I Sánchez.
Abstract
Katsuki-Jacobsen oxidation-epoxidation of acyclic alpha-silyloxy sulfinyl dienes, followed by acid-promoted cyclization, leads to 2,5-trans-sulfonyl dihydrofurans with good selectivities. As an application, the formal syntheses of (6S,7S,9R,10R)- and (6S,7S,9S,10S)-6,9-epoxynonadec-18-ene-7,10-diols is reported.Entities:
Mesh：
Substances：
Year: 2009 PMID： 19007180 DOI： 10.1021/jo801803m
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354