| Literature DB >> 18998730 |
Raju Dey1, Kalicharan Chattopadhyay, Brindaban C Ranu.
Abstract
The cross-coupling of allyl acetates and aryl and vinyl siloxanes proceeds readily by the catalysis of in situ generated palladium(0) nanoparticles. The reactions are stereoselective, and (E)-coupling products are obtained both from cis and trans allyl acetates. The coupling with vinyl siloxanes provides a novel protocol for the synthesis of 1,4-pentadienes.Entities:
Year: 2008 PMID: 18998730 DOI: 10.1021/jo802214m
Source DB: PubMed Journal: J Org Chem ISSN: 0022-3263 Impact factor: 4.354