Literature DB >> 18998635

Synthesis of directly and doubly linked dioxoisobacteriochlorin dimers.

Satoru Hiroto1, Ichiro Hisaki, Hiroshi Shinokubo, Atsuhiro Osuka.   

Abstract

Oxidation of 2,18-diborylporphyrin provided 2,18-dihydroxyporphyrin, which shows solvent-dependent keto-enol tautomerism and dimerization through hydrogen bonding interaction in solution. Further oxidation of 2,18-dihydroxyporphyrins afforded doubly and directly linked dioxoisobacteriochlorin face-to-face dimers.

Entities:  

Year:  2008        PMID： 18998635     DOI： 10.1021/ja807659h

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  2 in total

1.  Metalloporphyrin mixed-valence π-cation radicals: [Fe(oxoOEC(•/2))(Cl)]2SbCl6, structure, magnetic properties, and near-IR spectra.

Authors:  Ming Li; Teresa J Neal; Graeme R A Wyllie; Allen G Oliver; Charles E Schulz; W Robert Scheidt
Journal:  Inorg Chem       Date:  2011-08-02       Impact factor: 5.165

Review 2.  Transition metal catalyzed borylation of functional π-systems.

Authors:  Hiroshi Shinokubo
Journal:  Proc Jpn Acad Ser B Phys Biol Sci       Date:  2014       Impact factor: 3.493
  2 in total

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