Literature DB >> 18997943

Azaarene cis-dihydrodiol-derived 2,2'-bipyridine ligands for asymmetric allylic oxidation and cyclopropanation.

Derek R Boyd1, Narain D Sharma, Lenuta Sbircea, Deirdre Murphy, Tayeb Belhocine, John F Malone, Stuart L James, Christopher C R Allen, John T G Hamilton.   

Abstract

Biphenyl dioxygenase-catalysed cis-dihydroxylation of 2-chloroquinoline, 2-chloro-3-methylquinoline and 2-chloro-6-phenylpyridine substrates yielded the corresponding enantiopure cis-dihydrodiols; enantiopure 2,2'-bipyridines, synthesised in four steps from 2-chloroquinoline, proved to be efficient chiral ligands in catalytic asymmetric allylic oxidation and cyclopropanation reactions of alkenes.

Entities:  

Mesh：

Substances：

Year:  2008        PMID： 18997943     DOI： 10.1039/b814678k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Toluene Dioxygenase-Catalyzed cis-Dihydroxylation of Quinolines: A Molecular Docking Study and Chemoenzymatic Synthesis of Quinoline Arene Oxides.

Authors:  Derek R Boyd; Narain D Sharma; Pui L Loke; Jonathan G Carroll; Paul J Stevenson; Patrick Hoering; Christopher C R Allen
Journal:  Front Bioeng Biotechnol       Date:  2021-02-12

2.  Asymmetric radical carboesterification of dienes.

Authors:  Xiaotao Zhu; Wujun Jian; Meirong Huang; Daliang Li; Yajun Li; Xinhao Zhang; Hongli Bao
Journal:  Nat Commun       Date:  2021-11-18       Impact factor: 14.919

Review 3.  Monooxygenase- and Dioxygenase-Catalyzed Oxidative Dearomatization of Thiophenes by Sulfoxidation, cis-Dihydroxylation and Epoxidation.

Authors:  Derek R Boyd; Narain D Sharma; Paul J Stevenson; Patrick Hoering; Christopher C R Allen; Patrick M Dansette
Journal:  Int J Mol Sci       Date:  2022-01-14       Impact factor: 5.923
  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.