Literature DB >> 18991444

Rhodium-complex-catalyzed addition reactions of chloroacetyl chlorides to alkynes.

Taigo Kashiwabara1, Kouichiro Fuse, Ruimao Hua, Masato Tanaka.   

Abstract

The addition reaction of chloroacetyl chloride derivatives with terminal alkynes was found to be catalyzed by Rh(acac)(CO)(AsPh(3)) to afford (Z)-1,4-dichloro-3-buten-2-one derivatives, which displayed diverse reactivities in synthetic elaboration.

Entities:  

Year:  2008        PMID： 18991444     DOI： 10.1021/ol802260w

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Chloride-Tolerant Gold(I)-Catalyzed Regioselective Hydrochlorination of Alkynes.

Authors:  Rene Ebule; Shengzong Liang; Gerald B Hammond; Bo Xu
Journal:  ACS Catal       Date:  2017-09-07       Impact factor: 13.084

2.  Iridium-Catalyzed Hydrochlorination and Hydrobromination of Alkynes by Shuttle Catalysis.

Authors:  Peng Yu; Alessandro Bismuto; Bill Morandi
Journal:  Angew Chem Int Ed Engl       Date:  2020-01-16       Impact factor: 15.336

3.  One-Pot Synthesis of (Z)-β-Halovinyl Ketones via the Cascade of Sonogashira Coupling and Hydrohalogenation.

Authors:  Fa-Jie Chen; Zhenguo Hua; Jianhui Chen; Jiajia Chen; Daesung Lee; Yuanzhi Xia
Journal:  Front Chem       Date:  2021-04-22       Impact factor: 5.221
  3 in total

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