Fabrication of colloidal crystals with defined and complex structures via layer-by-layer transfer.

A new and versatile way--using poly(dimethylsiloxane) (PDMS) sheets to layer-by-layer (LbL) transfer hexagonal-close-packed particle monolayers from preformed colloidal crystals and stack them on substrates-has been demonstrated to create colloidal crystals. This approach allows LbL control of the thickness of the resulting crystals and especially of the size and the packing structure of the particles in each layer. Furthermore, it also allows fabrication of binary colloidal crystals over large areas by deformation of the PDMS sheets during LbL transfer. Two new binary crystals-one composed of identically sized particles but in different densities and the other of a nonclose-packed monolayer of large particles and a close-packed monolayer of small particles-were created, which are hard grown by other colloidal crystallization techniques developed thus far.