Literature DB >> 18985215

Deprotonative cadmation of functionalized aromatics.

Jean-Martial L'Helgoual'ch1, Ghenia Bentabed-Ababsa, Floris Chevallier, Mitsuhiro Yonehara, Masanobu Uchiyama, Aïcha Derdour, Florence Mongin.   

Abstract

This communication describes the deproto-metalation of a large range of aromatics including heterocycles using a newly developed lithium-cadmium base; the reaction proceeds at room temperature with an excellent chemoselectivity and efficiency, and proved to be regioselective in most cases.

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Year:  2008        PMID: 18985215     DOI: 10.1039/b809543d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  Recent advances in direct C-H arylation: Methodology, selectivity and mechanism in oxazole series.

Authors:  Cécile Verrier; Pierrik Lassalas; Laure Théveau; Guy Quéguiner; François Trécourt; Francis Marsais; Christophe Hoarau
Journal:  Beilstein J Org Chem       Date:  2011-11-29       Impact factor: 2.883

2.  Evaluating cis-2,6-dimethylpiperidide (cis-DMP) as a base component in lithium-mediated zincation chemistry.

Authors:  David R Armstrong; Jennifer A Garden; Alan R Kennedy; Sarah M Leenhouts; Robert E Mulvey; Philip O'Keefe; Charles T O'Hara; Alan Steven
Journal:  Chemistry       Date:  2013-08-19       Impact factor: 5.236

3.  Transforming LiTMP Lithiation of Challenging Diazines through Gallium Alkyl Trans-Metal-Trapping.

Authors:  Marina Uzelac; Alan R Kennedy; Eva Hevia; Robert E Mulvey
Journal:  Angew Chem Int Ed Engl       Date:  2016-10-10       Impact factor: 15.336

  3 in total

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