Literature DB >> 18985197

Encapsulated molecular catalysts in polysiloxane gels: ruthenium cluster-catalyzed isomerization of alkenes.

Yukihiro Motoyama1, Motonori Abe, Kazuyuki Kamo, Yusuke Kosako, Hideo Nagashima.   

Abstract

Novel ruthenium-encapsulating polysiloxane gels are prepared by treatment of polymethylhydrosiloxane with diols in the presence of (mu(3),eta(2),eta(3),eta(5)-acenaphthylene)Ru(3)(CO)(7), and act as reusable catalysts in the isomerization of alkenes without leakage of the catalyst species.

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Year:  2008        PMID: 18985197     DOI: 10.1039/b809937e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Stereocontrolled cyanohydrin ether synthesis through chiral Brønsted acid-mediated vinyl ether hydrocyanation.

Authors:  Chunliang Lu; Xiaoge Su; Paul E Floreancig
Journal:  J Org Chem       Date:  2013-09-04       Impact factor: 4.354

  1 in total

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