Literature DB >> 18962380

Study of the tautomeric forms of 3,4-dihydroxyphenylacetic acid by carbon-13 nuclear magnetic resonance spectroscopy.

T Ishimitsu1, Y Fujiwara, S Hirose.   

Abstract

The pH-dependent (13)C chemical shifts indicate an approximately 1:1 ratio of the 3-OH:4-OH tautomeric forms of singly dissociated 3,4-dihydroxyphenylacetic acid. It is found that the (13)C chemical-shift method is an effective technique for determining tautomeric forms from pK values.

Entities:  

Year:  1979        PMID: 18962380     DOI: 10.1016/0039-9140(79)80160-5

Source DB:  PubMed          Journal:  Talanta        ISSN: 0039-9140            Impact factor:   6.057


  1 in total

1.  pH-dependent studies reveal an efficient hydroxylation mechanism of the oxygenase component of p-hydroxyphenylacetate 3-hydroxylase.

Authors:  Nantidaporn Ruangchan; Chanakan Tongsook; Jeerus Sucharitakul; Pimchai Chaiyen
Journal:  J Biol Chem       Date:  2010-10-28       Impact factor: 5.157

  1 in total

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