| Literature DB >> 18959423 |
I-Hon Chen1, Kounosuke Oisaki, Motomu Kanai, Masakatsu Shibasaki.
Abstract
A general catalytic method for the hetero-Diels-Alder reaction between Danishefsky-type siloxy dienes and ketones was developed. Optimum results were produced with a catalyst generated from CuOTf x (C6H6)1/2 and TBAT with Ph 3PO as the catalytic additive. This reaction was extended to an asymmetric variant, using a Cu(I)-Walphos catalyst.Entities:
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Year: 2008 PMID： 18959423 DOI： 10.1021/ol802134a
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005