Literature DB >> 18956070

Heavier group 2 element-catalysed hydroamination of isocyanates.

Anthony G M Barrett1, Tanya C Boorman, Mark R Crimmin, Michael S Hill, Gabriele Kociok-Köhn, Panayiotis A Procopiou.   

Abstract

The heteroleptic calcium amides [{ArNC(Me)CHC(Me)NAr}Ca(NR(2))(THF)] (Ar=2,6-di-iso-propylphenyl, R=SiMe(3), Ph) and the homoleptic heavier alkaline earth amides, [M{N(SiMe(3))(2)}(2)] (M=Ca, Sr and Ba) are reported as pre-catalysts for the hydroamination of isocyanates.

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Year:  2008        PMID: 18956070     DOI: 10.1039/b809649j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

Review 1.  Main group bimetallic partnerships for cooperative catalysis.

Authors:  Jose M Gil-Negrete; Eva Hevia
Journal:  Chem Sci       Date:  2020-10-16       Impact factor: 9.825

  1 in total

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