Literature DB >> 18956033

Axial chirality control of tropos BIPHEP-Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation.

Kohsuke Aikawa1, Yūki Takabayashi, Susumu Kawauchi, Koichi Mikami.   

Abstract

Diastereopure tropos Rh complexes bearing not only BIPHEP but also chiral dienes can be employed as highly enantioselective hydrogenation catalysts for an olefinic substrate.

Entities:  

Year:  2008        PMID： 18956033     DOI： 10.1039/b809683j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Stereodynamic tetrahydrobiisoindole "NU-BIPHEP(O)"s: functionalization, rotational barriers and non-covalent interactions.

Authors:  Golo Storch; Sebastian Pallmann; Frank Rominger; Oliver Trapp
Journal:  Beilstein J Org Chem       Date:  2016-07-14       Impact factor: 2.883

2.  Enantiodivergent asymmetric catalysis with the tropos BIPHEP ligand and a proline derivative as chiral selector.

Authors:  P Oczipka; D Müller; W Leitner; G Franciò
Journal:  Chem Sci       Date:  2015-10-29       Impact factor: 9.825
  2 in total

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