Literature DB >> 18956032

Enantiomerically pure bicyclo[3.3.1]nona-2,6-diene as the sole source of enantioselectivity in BIPHEP-Rh asymmetric hydrogenation.

Tharmalingam Punniyamurthy1, Monika Mayr, Alexander S Dorofeev, Carole J R Bataille, Silvia Gosiewska, Bao Nguyen, Andrew R Cowley, John M Brown.   

Abstract

In situ resolution of the rapidly racemising diphosphine BIPHEP and its relatives with the cationic Rh complex of (S,S)-bicyclonona-2,6-diene permits the asymmetric hydrogenation of dehydroamino esters.

Entities:  

Year:  2008        PMID： 18956032     DOI： 10.1039/b807669c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Stereodynamic tetrahydrobiisoindole "NU-BIPHEP(O)"s: functionalization, rotational barriers and non-covalent interactions.

Authors:  Golo Storch; Sebastian Pallmann; Frank Rominger; Oliver Trapp
Journal:  Beilstein J Org Chem       Date:  2016-07-14       Impact factor: 2.883

2.  Enantiodivergent asymmetric catalysis with the tropos BIPHEP ligand and a proline derivative as chiral selector.

Authors:  P Oczipka; D Müller; W Leitner; G Franciò
Journal:  Chem Sci       Date:  2015-10-29       Impact factor: 9.825
  2 in total

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