Literature DB >> 18931756

Generation and reactivity of the dehydrotropylium-Co2(CO)6 ion.

Sheida Amiralaei1, James R Green.   

Abstract

Dehydrotropylium-Co(2)(CO)(6) ion (2) has been generated by the Lewis acid mediated ionization of alcohol (3); it is attacked by relatively strong nucleophiles (N>1), but undergoes a radical homocoupling in the presence of weak nucleophiles (N<1).

Entities:  

Year:  2008        PMID: 18931756     DOI: 10.1039/b812174e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Generation and Reactions of a Benzodehydrotropylium Ion-Co2(CO)6 Complex.

Authors:  Mariam A Mehdi; Eric A C Bushnell; Sahar Nikoo; James W Gauld; James R Green
Journal:  ACS Omega       Date:  2019-10-28
  1 in total

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