Literature DB >> 18855394

Molecular structure of a cyclopropyl substituted vinyl cation.

Andrea Klaer1, Wolfgang Saak, Detlev Haase, Thomas Müller.   

Abstract

The experimentally determined molecular structure of vinyl cation 1 provides clear evidence for the occurrence of extended sigma-conjugation involving the cyclopropyl ring and the beta-C-Si bonds.

Entities:  

Year:  2008        PMID： 18855394     DOI： 10.1021/ja8069055

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  4 in total

1.  Reactive p-block cations stabilized by weakly coordinating anions.

Authors:  Tobias A Engesser; Martin R Lichtenthaler; Mario Schleep; Ingo Krossing
Journal:  Chem Soc Rev       Date:  2015-11-27       Impact factor: 54.564

2.  IR-Spectroscopic and X-ray-Structural Study of Vinyl-Type Carbocations in Their Carborane Salts.

Authors:  Evgenii S Stoyanov; Irina Yu Bagryanskaya; Irina V Stoyanova
Journal:  ACS Omega       Date:  2022-07-29

3.  Planar Cyclopenten-4-yl Cations: Highly Delocalized π Aromatics Stabilized by Hyperconjugation.

Authors:  Samuel Nees; Thomas Kupfer; Alexander Hofmann; Holger Braunschweig
Journal:  Angew Chem Int Ed Engl       Date:  2020-08-25       Impact factor: 16.823

4.  Unsaturated Vinyl-Type Carbocation [(CH3)2C=CH]+ in Its Carborane Salts.

Authors:  Evgenii S Stoyanov; Irina Yu Bagryanskaya; Irina V Stoyanova
Journal:  ACS Omega       Date:  2021-06-10
  4 in total

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