| Literature DB >> 18844408 |
Atsushi Nagai1, Kenta Kokado, Yuuya Nagata, Manabu Arita, Yoshiki Chujo.
Abstract
Diarylboron diketonates were successfully prepared by the reaction of 1,3-diketone derivatives and arylboron compounds such as triphenylborane [BPh3] and fluorobis(pentafluorophenyl)borane diethyl etherate [(C6F5)2BF x OEt2]. The fluorescent emission of their complexes took place depending on the substituent of the arylboron moiety. In particular, a boron 1,3-bis(4-methoxyphenyl)-1,3-diketonate chelated by a strong electron-withdrawing C6F5 group exhibited the most intense fluorescence.Entities:
Year: 2008 PMID: 18844408 DOI: 10.1021/jo8017582
Source DB: PubMed Journal: J Org Chem ISSN: 0022-3263 Impact factor: 4.354