Literature DB >> 18844408

Highly intense fluorescent diarylboron diketonate.

Atsushi Nagai1, Kenta Kokado, Yuuya Nagata, Manabu Arita, Yoshiki Chujo.   

Abstract

Diarylboron diketonates were successfully prepared by the reaction of 1,3-diketone derivatives and arylboron compounds such as triphenylborane [BPh3] and fluorobis(pentafluorophenyl)borane diethyl etherate [(C6F5)2BF x OEt2]. The fluorescent emission of their complexes took place depending on the substituent of the arylboron moiety. In particular, a boron 1,3-bis(4-methoxyphenyl)-1,3-diketonate chelated by a strong electron-withdrawing C6F5 group exhibited the most intense fluorescence.

Entities:  

Year:  2008        PMID: 18844408     DOI: 10.1021/jo8017582

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  2 in total

1.  Aromatic difluoroboron β-diketonate complexes: effects of π-conjugation and media on optical properties.

Authors:  Songpan Xu; Ruffin E Evans; Tiandong Liu; Guoqing Zhang; J N Demas; Carl O Trindle; Cassandra L Fraser
Journal:  Inorg Chem       Date:  2013-03-19       Impact factor: 5.165

2.  Efficient solid-state emission and reversible mechanofluorochromism of a tetraphenylethene-pyrene-based β-diketonate boron complex.

Authors:  Ting Sun; Feng Zhao; Gaolei Xi; Jian Gong; Mengyu Sun; Chang Dong; Jingyi Qiu
Journal:  RSC Adv       Date:  2019-06-24       Impact factor: 4.036

  2 in total

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