| Literature DB >> 18843406 |
Caroline Aciro1, Stephen G Davies, Paul M Roberts, Angela J Russell, Andrew D Smith, James E Thomson.
Abstract
The ammonium-directed, metal-free oxidation of 3-(N,N-dibenzylamino)cyclohex-1-ene with mCPBA in the presence of either trichloroacetic acid or tosic acid has been used as the key step to facilitate the synthesis of all the diastereoisomers of 3-aminocyclohexane-1,2-diol, in >98% de in each case.Entities:
Mesh：
Substances：
Year: 2008 PMID： 18843406 DOI： 10.1039/b808812h
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876