Literature DB >> 18834136

One-pot formation of allylic chlorides from carbonyl derivatives.

Matthew J Fuchter1, Jean-Noël Levy.   

Abstract

An efficient, one-pot method for the conversion of carbonyl electrophiles to allylic chlorides has been developed, by activating magnesium alkoxides in situ using TiCl4.

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Year:  2008        PMID： 18834136     DOI： 10.1021/ol802026u

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Allylic and allenic halide synthesis via NbCl(5)- and NbBr(5)-mediated alkoxide rearrangements.

Authors:  P C Ravikumar; Lihua Yao; Fraser F Fleming
Journal:  J Org Chem       Date:  2009-10-02       Impact factor: 4.354

2.  Direct Conversion of Aldehydes and Ketones to Allylic Halides by a NbX(5-)[3,3] Rearrangement.

Authors:  Fraser F Fleming; P C Ravikumar; Lihua Yao
Journal:  Synlett       Date:  2009       Impact factor: 2.454

3.  3-Chloro-1-lithiopropene, a functional organolithium reagent, and its reactions with alkylboronates to give 3-alkylprop-1-en-3-ols.

Authors:  Keith Smith; Mark C Elliott; D Heulyn Jones
Journal:  J Org Chem       Date:  2013-09-11       Impact factor: 4.354
  3 in total

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