Literature DB >> 18830502

Bromine-lithium exchange under non-cryogenic conditions: TMSCH(2)Li-LiDMAE promoted C-2 lithiation of 2,3-dibromopyridine.

Philippe C Gros1, Fatima Elaachbouni.   

Abstract

The first C-2 selective bromine-lithium exchange in 2,3-dibromopyridine was performed at 0 degrees C in toluene using the TMSCH(2)Li-LiDMAE reagent.

Entities:  

Year:  2008        PMID: 18830502     DOI: 10.1039/b810453k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Large-scale solvent-free chlorination of hydroxy-pyrimidines, -pyridines, -pyrazines and -amides using equimolar POCl₃.

Authors:  Han Wang; Kun Wen; Le Wang; Ye Xiang; Xiaocheng Xu; Yongjia Shen; Zhihua Sun
Journal:  Molecules       Date:  2012-04-16       Impact factor: 4.411

  1 in total

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