Literature DB >> 18816114

Design of liquid crystals with "de Vries-like" properties: organosiloxane mesogen with a 5-phenylpyrimidine core.

Jeffrey C Roberts1, Nadia Kapernaum, Frank Giesselmann, Robert P Lemieux.   

Abstract

According to a new design strategy for "de Vries-like" liquid crystal materials, we report the synthesis and characterization of an organosiloxane mesogen with a 5-phenylpyrimidine core that forms SmA and SmC liquid crystal phases. This new material is characterized by a maximum layer contraction of 1.2% upon SmA-SmC phase transition and is comparable to the best "de Vries-like" materials reported heretofore.

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Year:  2008        PMID: 18816114     DOI: 10.1021/ja805672q

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  3 in total

1.  Influence of spacer chain lengths and polar terminal groups on the mesomorphic properties of tethered 5-phenylpyrimidines.

Authors:  Gundula F Starkulla; Elisabeth Kapatsina; Angelika Baro; Frank Giesselmann; Stefan Tussetschläger; Martin Kaller; Sabine Laschat
Journal:  Beilstein J Org Chem       Date:  2009-11-09       Impact factor: 2.883

2.  Fluorenone imidazolium salts as novel de Vries materials.

Authors:  Korinna Bader; Carsten Müller; Yann Molard; Angelika Baro; Philipp Ehni; Jakob Knelles; Sabine Laschat
Journal:  RSC Adv       Date:  2020-06-23       Impact factor: 4.036

3.  Observation of "de Vries-like" properties in bent-core molecules.

Authors:  Supreet Kaur; Abinash Barthakur; Golam Mohiuddin; Santosh Prasad Gupta; Surajit Dhara; Santanu Kumar Pal
Journal:  Chem Sci       Date:  2022-01-18       Impact factor: 9.825

  3 in total

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