| Literature DB >> 18811204 |
Abstract
Mintlactone is synthesized in a concise and efficient way by using a highly diastereoselective intramolecular propargylic Barbier reaction, followed by an allenol cyclocarbonylation. Tin(II) chloride is found to be the most effective reagent for the Barbier reaction.Entities:
Mesh:
Substances:
Year: 2008 PMID: 18811204 DOI: 10.1021/jo801433f
Source DB: PubMed Journal: J Org Chem ISSN: 0022-3263 Impact factor: 4.354