Literature DB >> 18802600

BiPh3--a convenient synthon for heavy alkaline-earth metal amides.

Miriam M Gillett-Kunnath1, Jonathan G MacLellan, Craig M Forsyth, Philip C Andrews, Glen B Deacon, Karin Ruhlandt-Senge.   

Abstract

Environmentally friendly, commercially available BiPh3 reacts with heavy alkaline-earth metals (Ae) and bulky trimethylsilylamines to give the corresponding amides [Ae{N(SiMe3)(R)}2(thf)n] (R=SiMe3, 2,4,6-Me3C6H2, 2,6-iPr2C6H3) in good yields, providing proof of concept for a general synthetic method.

Entities:  

Year:  2008        PMID: 18802600     DOI: 10.1039/b806948d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  When VSEPR fails: experimental and theoretical investigations of the behavior of alkaline-earth-metal acetylides.

Authors:  Marites A Guino-o; Jacob S Alexander; Michael L McKee; Håkon Hope; Ulrich B Englich; Karin Ruhlandt-Senge
Journal:  Chemistry       Date:  2009-11-09       Impact factor: 5.236

Review 2.  Bismuth Redox Catalysis: An Emerging Main-Group Platform for Organic Synthesis.

Authors:  Hye Won Moon; Josep Cornella
Journal:  ACS Catal       Date:  2022-01-07       Impact factor: 13.084

  2 in total

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